Acta Crystallographica Section E (Feb 2012)

Diaquabis(hydrogen tartrato)cobalt(II) dihydrate

  • Chao-Jun Du,
  • Qun-An Zhang,
  • Li-Sheng Wang,
  • Chao-Ling Du

DOI
https://doi.org/10.1107/S1600536811054390
Journal volume & issue
Vol. 68, no. 2
pp. m99 – m100

Abstract

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The title complex, [Co(C4H5O6)2(H2O)2]·2H2O, contains a CoII ion, two single deprotonated tartrate anions, two coordinated water molecules and two lattice water molecules. The coordination geometry of the CoII ion is a distorted octahedron with two O atoms from two coordinated water molecules occupying cis positions in the equatorial plane and four O atoms from two hydrogen tartrate ions occupying the remaining positions. In the crystal, intermolecular O—H...O hydrogen bonds link the molecules into a three-dimensional network.