Acta Crystallographica Section E (Oct 2010)

Bis{1-[(E)-o-tolyldiazenyl]-2-naphtholato}copper(II)

  • Bao-Tsan Ko,
  • Chen-Yu Li,
  • Chi-Huan Li,
  • Wan-Ju Tai

DOI
https://doi.org/10.1107/S1600536810037888
Journal volume & issue
Vol. 66, no. 10
pp. m1315 – m1315

Abstract

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In the title complex, [Cu(C17H13N2O)2], the CuII atom is tetracoordinated by two N atoms and two O atoms from two bidentate 1-[(E)-o-tolyldiazenyl]-2-naphtholate ligands, forming a slightly distorted square-planar environment. The two N atoms and two O atoms around the CuII atom are trans to each other, with an O—Cu—O bond angle of 177.00 (9)° and an N—Cu—N bond angle of 165.63 (10)°. The average distances between the CuII atom and the coordinated O and N atoms are 1.905 (2) and 1.995 (2)Å, respectively.