Excellent Energy Storage and Photovoltaic Performances in Bi0.45Na0.45Ba0.1TiO3-Based Lead-Free Ferroelectricity Thin Film

Jianhua Wu; Tiantian Zhang; Xing Gao; Lei Ning; Yanhua Hu; Xiaojie Lou; Yunying Liu; Ningning Sun; Yong Li

doi:10.3390/ceramics7030068

Ceramics (Aug 2024)

Excellent Energy Storage and Photovoltaic Performances in Bi0.45Na0.45Ba0.1TiO3-Based Lead-Free Ferroelectricity Thin Film

Jianhua Wu,
Tiantian Zhang,
Xing Gao,
Lei Ning,
Yanhua Hu,
Xiaojie Lou,
Yunying Liu,
Ningning Sun,
Yong Li

Affiliations

Jianhua Wu: Inner Mongolia Key Laboratory of Ferroelectric-Related New Energy Materials and Devices, School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
Tiantian Zhang: Inner Mongolia Key Laboratory of Ferroelectric-Related New Energy Materials and Devices, School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
Xing Gao: Inner Mongolia Key Laboratory of Ferroelectric-Related New Energy Materials and Devices, School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
Lei Ning: Inner Mongolia Key Laboratory of Ferroelectric-Related New Energy Materials and Devices, School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
Yanhua Hu: Department of Chemical Engineering, Ordos Institute of Technology, Erdos 017000, China
Xiaojie Lou: State Key Laboratory for Mechanical Behavior of Materials, Frontier Institute of Science and Technology, Xi’an Jiaotong University, Xi’an 710049, China
Yunying Liu: Inner Mongolia Key Laboratory of Ferroelectric-Related New Energy Materials and Devices, School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
Ningning Sun: Inner Mongolia Key Laboratory of Ferroelectric-Related New Energy Materials and Devices, School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
Yong Li: Inner Mongolia Key Laboratory of Ferroelectric-Related New Energy Materials and Devices, School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China

DOI: https://doi.org/10.3390/ceramics7030068
Journal volume & issue: Vol. 7, no. 3
pp. 1043 – 1052

Abstract

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Inorganic dielectric films have attracted extensive attention in the field of microelectronic and electrical devices because of their wide operating temperature range, small size, and easy integration. Here, we designed and prepared eco-friendly (1-x)Bi0.45Na0.45Ba0.1TiO3-xBi(Mg1/3Nb2/3)O3 multifunctional ferroelectric thin films for energy storage and photovoltaic. The results show that Bi(Mg1/3Nb2/3)O3 can effectively improve the energy storage performance. At x = 0.05, the energy storage density and efficiency are as high as 73.1 J/cm3 and 86.2%, respectively, and can operate stably in a wide temperature range. The breakdown field strength of the thin films increased significantly, and the analysis showed that the addition of Bi(Mg1/3Nb2/3)O3 caused a change in the internal conduction mechanism. At the same time, the generation of polar nanoregions increases the relaxation characteristics, thus improving the energy storage properties. In addition, the thin film material also has excellent ferroelectric photovoltaic properties. This work represents a new design paradigm that can serve as an effective strategy for developing advanced multi-functional materials.

Published in Ceramics

ISSN: 2571-6131 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Technology: Chemical technology
Website: https://www.mdpi.com/journal/ceramics

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