Hexaethylguanidinium Salts

Robert Salchner; Volker Kahlenberg; Thomas Gelbrich; Klaus Wurst; Martin Rauch; Gerhard Laus; Herwig Schottenberger

doi:10.3390/cryst4030404

Crystals (Sep 2014)

Hexaethylguanidinium Salts

Robert Salchner,
Volker Kahlenberg,
Thomas Gelbrich,
Klaus Wurst,
Martin Rauch,
Gerhard Laus,
Herwig Schottenberger

Affiliations

Robert Salchner: Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria
Volker Kahlenberg: Institute of Mineralogy and Petrography, University of Innsbruck, 6020 Innsbruck, Austria
Thomas Gelbrich: Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria
Klaus Wurst: Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria
Martin Rauch: Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria
Gerhard Laus: Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria
Herwig Schottenberger: Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria

DOI: https://doi.org/10.3390/cryst4030404
Journal volume & issue: Vol. 4, no. 3
pp. 404 – 416

Abstract

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Crystal structures of five hexaethylguanidinium salts (PF6− 1, FeCl4− 2, CuCl42−·H2O 3, CoBr42−/Br−·H2O 4, bistriflimide 5) were determined. Short interionic contacts were identified. Cyclic voltammetry of 2 revealed an electrochemical window from +1.0 to −1.5 V with a single Fe(III)/Fe(II) redox event at −0.27 V on a gold electrode versus Ag/AgCl.

Published in Crystals

ISSN: 2073-4352 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Crystallography
Website: http://www.mdpi.com/journal/crystals/

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