AIP Advances (Mar 2015)

Ferroelectric domain structures in <001>-oriented K0.15Na0.85NbO3 lead-free single crystal

  • Yan Chen,
  • Chi-Man Wong,
  • Hao Deng,
  • Hei-Man Yau,
  • Danyang Wang,
  • Zhibo Yan,
  • Haosu Luo,
  • Helen L. W. Chan,
  • Jiyan Dai

DOI
https://doi.org/10.1063/1.4914936
Journal volume & issue
Vol. 5, no. 3
pp. 037117 – 037117-6

Abstract

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In this work, ferroelectric domain structures of -oriented K0.15Na0.85NbO3 single crystal are characterized. Transmission electron microscopy (TEM) observation revealed high-density of laminate domain structures in the crystal and the lattices of the neighboring domains are found to be twisted in a small angle. Superlattice diffraction spots of 1 2 { eeo } and 1 2 { ooe } in electron diffraction patterns are observed in the crystal, revealing the a+a+c− tilting of oxygen octahedral in the perovskite structure. The piezoresponse of domains and in-situ poling responses of K0.15Na0.85NbO3 crystal are observed by piezoresponse force microscopy (PFM), and the results assure its good ferroelectric properties.