Nano-Micro Letters (Nov 2023)
Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction
- Kangwang Wang,
- Zhuofeng Hu,
- Peifeng Yu,
- Alina M. Balu,
- Kuan Li,
- Longfu Li,
- Lingyong Zeng,
- Chao Zhang,
- Rafael Luque,
- Kai Yan,
- Huixia Luo
Affiliations
- Kangwang Wang
- School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen University
- Zhuofeng Hu
- School of Environmental Science and Engineering, Sun Yat-Sen University
- Peifeng Yu
- School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen University
- Alina M. Balu
- Departamento de Química Orgánica, Universidad de Córdoba
- Kuan Li
- School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen University
- Longfu Li
- School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen University
- Lingyong Zeng
- School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen University
- Chao Zhang
- School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen University
- Rafael Luque
- Center for Refining and Advanced Chemicals, King Fahd University of Petroleum and Minerals
- Kai Yan
- School of Environmental Science and Engineering, Sun Yat-Sen University
- Huixia Luo
- School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen University
- DOI
- https://doi.org/10.1007/s40820-023-01221-3
- Journal volume & issue
-
Vol. 16,
no. 1
pp. 1 – 17
Abstract
Highlights The S-vacancies result in the change of d-band electronic state of Mo. An internal quantum efficiency of 94.01% at 380 nm for photocatalytic CO2 reduction reaction (CO2RR). The Mo–S bridging bonds optimize adsorption energies and accelerate CO2RR kinetics.
Keywords
