Unconventional Resources (Jan 2024)
Diagenetic characteristics and microscopic pore evolution of deep shale gas reservoirs in Longmaxi Formation, Southeastern Sichuan basin, China
Abstract
The Lower Silurian Longmaxi Formation is the favorable target area for deep shale gas exploration and development in southeastern Sichuan Basin. Based on whole-rock X-ray diffraction analysis, scanning electron microscope, reservoir evolution thermal simulation experiment and nitrogen adsorption experiment, the diagenetic characteristics of deep shale reservoir in Longmaxi Formation were analyzed, and the reservoir pore evolution law was clarified. The results show that: ①The diagenetic minerals of the deep shale in the Longmaxi Formation are mainly quartz and clay minerals, with a small amount of carbonate minerals and feldspar. The primary inorganic pores are mainly controlled by mechanical compaction and cementation (quartz, carbonate, clay, pyrite). The organic pores are mainly controlled by the thermal maturity of organic matter, dissolution and later compaction. ②In the process of thermal simulation experiment, the organic pores of shale show a process of change from scratch, from small to large and then from large to small. Later, the organic matter is affected by compaction and graphitization, and the volume of micropores and mesopores begins to decrease. ③The shale pores of Longmaxi Formation have undergone several evolutionary stages. In the early stage of diagenesis, compaction caused a large number of inorganic pores to disappear. In the middle stage of diagenesis, kerogen hydrocarbon generation occupied pores, dissolution and cementation transformed pores. In the late diagenetic period, liquid hydrocarbon cracking gas and pressurization promote the development of organic pores.
