Acta Crystallographica Section E (Oct 2012)

5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide

  • Mehmet Akkurt,
  • İsmail Çelik,
  • Füsun Kazan Gürbüzel,
  • Sumru Özkırımlı,
  • Orhan Büyükgüngör

DOI
https://doi.org/10.1107/S1600536812039347
Journal volume & issue
Vol. 68, no. 10
pp. o2969 – o2970

Abstract

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In the title compound, C25H17ClF3N3O2S, the five-membered 1,3-thiazolidine ring adopts a twist conformation. The three F atoms of the CF3 group are disordered over two sets of sites with refined occupancies of 0.542 (18) and 0.458 (18). In the nine-membered 1H-indoline ring system, the 1H-pyrrole ring forms a dihedral angle of 4.7 (2)° with the benzene ring, while it is twisted at an angle of 46.5 (2)° with respect to the attached phenyl ring. The dihedral angle between the phenyl and trifluoromethyl-substituted benzene rings is 56.0 (2)°. In the crystal, N—H...O hydrogen bonds connect the molecules into a three-dimensional network. In addition, weak C—H...O hydrogen bonds and weak C—H...π interactions are observed.