Enhanced electrochemical performance of molten salt synthesized V2CTx MXene@VOx composite in Zn ion aqueous electrolytes

Abstract

The development of MXenes using Lewis acidic salts for etching (MS-MXenes) in molten salts presents a novel, fluorine-free method attracting considerable interest. However, the behavior of various MS-MXenes and their derivatives in aqueous environments remains largely unexplored. Particularly, vanadium-based MXenes demonstrate intriguing properties in Zn ion aqueous electrolytes. Herein, a fluorine-free V2CTx MXene@VOx is synthesized by molten salt etching under an argon atmosphere. The electrochemical properties of V2CTx@VOx are tested in various aqueous electrolytes, including Zn(TFSI)2, ZnSO4, ZnBr2, ZnAc2, and ZnCl2 solutions. The V2CTx@VOx shows high redox capacities in all these Zn ion electrolytes, with the peak performance observed in 1 M ZnBr2, achieving a maximum capacity of 172 mAh g−1 at 1 mV s−1. This performance rivals that of V2CTx MXene prepared through wet-chemical methods. These results underscore the potential of MS-MXenes materials in aqueous energy storage applications.

Keywords

• V2CTx
• MXene
• Composite
• Batteries – aqueous
• Energy storage