Evolution of Viscosity and Structure Property during the Two-step Reduction of Vanadium Slags

Abstract

This is an article in the field of metallurgical engineering. At present, the cumbersome product routing of FeV alloy causes high energy consumption and hazardous leaching liquor waste. Therefore, a two-step direct reduction to produce FeV alloy from vanadium slags using photovoltaic silicon wafer cutting waste and aluminum ash as reductant, was investigated to solve the above problems. In the present work, the evolution of viscosity and the melt structure during the two-step reduction process of vanadium slags was investigated. The results showed that at 1 873 K, FeO-V2O3-Cr2O3-MnO-SiO2-TiO2-CaO slag system corresponding to the prereduction process, with the decrease of FeO content and the increase of SiO2 content in the slags, the size of FeCr2O4 spinel decreased gradually. The transition of the main influencing factor of the melt structure from FeO to SiO2 resulted in the increase of structure complexity, the structural complexity of the slag system increased from 0.176 to 2.517, the viscosity of the slag system increased from 0.092 Pa·s to 0.476 Pa·s. FeO-Cr2O3-MnO-V2O3-Al2O3-SiO2-TiO2-CaO slag system corresponding to the final reduction process, with the decrease of FeO, Cr2O3, MnO, V2O3 content and the increase of Al2O3 content in the slag, the size of MnCr2O4 spinel decreased gradually and the slag system comprised from a solid-liquid mixture to liquid, the transition of the main influencing factor from SiO2 to Al2O3 resulted in the transformation of the main structure of the slag system from silicate to aluminosilicate, the structural complexity of the slag system increased from 0.252 to 2.248, and the viscosity of the slag system increased from 0.091 Pa·s to 0.372 Pa·s.

Keywords

• metallurgical engineering
• two-step reduction
• vanadium slags
• viscosity
• melt structure
• structural complexity