Thermodynamic perturbation theory and equation of state developments

Abstract

An alternative way of utilizing the thermodynamic perturbation theory of Wertheim for the development of equations of state for associating fluid models is presented and detailed for water. The approach makes use of general features of the parameter of non-saturation to avoid the necessary solution of an algebraic equation and unbinds the results from a tight dependence on details of the simple reference fluid model used in the perturbation theory.

Keywords

• primitive model of water
• saft equations of state
• van der waals methodology
• thermodynamic perturbation theory