Employing nutraceutical industry by-product, cumin seeds spent, for the adsorption treatment of acid blue 113 dye

Syed Noeman Taqui; Usman Taqui Syed; Sameer Algburi; Rayees Afzal Mir; Akheel Ahmed Syed; Abdullah I. Al-Mansour; Shamshad Alam; Mohammad Amir khan; Shareefraza J. Ukkund

doi:10.1063/5.0217877

AIP Advances (Sep 2024)

Employing nutraceutical industry by-product, cumin seeds spent, for the adsorption treatment of acid blue 113 dye

Syed Noeman Taqui,
Usman Taqui Syed,
Sameer Algburi,
Rayees Afzal Mir,
Akheel Ahmed Syed,
Abdullah I. Al-Mansour,
Shamshad Alam,
Mohammad Amir khan,
Shareefraza J. Ukkund

Affiliations

Syed Noeman Taqui: Department of Chemistry, Bharathi College-Post Graduate and Research Centre, Bharathi Nagara, Karnataka 571422, India
Usman Taqui Syed: LAQV-REQUIMTE, Department of Chemistry, Faculty of Science and Technology, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal
Sameer Algburi: Al-Kitab University, Kirkuk, Iraq
Rayees Afzal Mir: Glocal School of Agricultural Science, Glocal University, Mirzapur pole, Saharanpur, Uttar Pradesh 247121, India
Akheel Ahmed Syed: Centre for Advanced Research and Innovation, Glocal University, Delhi-Yamunotri Marg, SH - 57, Mirzapur Pole, Saharanpur District, Uttar Pradesh 247121, India
Abdullah I. Al-Mansour: Department of Civil Engineering, College of Engineering, King Saud University, Riyadh 11421, Saudi Arabia
Shamshad Alam: Department of Civil Engineering, College of Engineering, King Saud University, Riyadh 11421, Saudi Arabia
Mohammad Amir khan: Department of Civil Engineering, Galgotias College of Engineering, Knowledge Park 11, Greater Noida 201310, India
Shareefraza J. Ukkund: Department of Biotechnology, P. A. College of Engineering, Mangalore 574153, India

DOI: https://doi.org/10.1063/5.0217877
Journal volume & issue: Vol. 14, no. 9
pp. 095034 – 095034-13

Abstract

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The aim of this study is to discover the potential use of nutraceutical industrial cumin seed spent (NICUS) as an economical biosorbent for eliminating acid blue 113 (AB113), an azo dye, from water. The study investigates the influence of pH, adsorbent dosage, temperature, particle size, and initial dye concentration on the adsorption of AB113. Various isotherm models and kinetic models were studied. At equilibrium situations, the maximum trial adsorption volume (qe) was found to be 96 mg g−1. The main objective was to determine the suitability of the pseudo-second-order model for describing the kinetics of adsorption. Thermodynamic parameters ΔG0 ΔH0 ΔS0 revealed that the adsorption process was endothermic and non-spontaneous. The lower value of ΔH0 suggests a physical adsorption process. Analysis using FTIR and SEM spectra confirmed that the NICUS surface effectively adsorbed AB113. NICUS emerges as a promising adsorbent for the efficient deduction of AB113 from aqueous solutions.

Published in AIP Advances

ISSN: 2158-3226 (Online)
Publisher: AIP Publishing LLC
Country of publisher: United States
LCC subjects: Science: Physics
Website: http://aipadvances.aip.org/

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