Effective immobilisation of a metathesis catalyst bearing an ammonium-tagged NHC ligand on various solid supports

Abstract

An ammonium-tagged ruthenium complex, 8, was deposited on several widely available commercial solid materials such as silica gel, alumina, cotton, filter paper, iron powder or palladium on carbon. The resulting catalysts were tested in toluene or ethyl acetate, and found to afford metathesis products in high yield and with extremely low ruthenium contamination. Depending on the support used, immobilised catalyst 8 shows also additional traits, such as the possibility of being magnetically separated or the use for metathesis and subsequent reduction of the obtained double bond in one pot.

Keywords

• catalysis
• immobilisation
• N-heterocyclic carbenes
• olefin metathesis
• ruthenium