Nature Communications (Feb 2019)
Lithium promoted mesoporous manganese oxide catalyzed oxidation of allyl ethers
Abstract
Acrylics and acrylates have become important building blocks for the chemical industry, but their efficient synthesis remains a challenge. Here, the authors report the first example of the catalytic aerobic partial oxidation of allyl ether to its acrylate ester derivative using a Li ion promoted mesoporous manganese oxide under mild conditions.