Nature Communications (Feb 2019)

Lithium promoted mesoporous manganese oxide catalyzed oxidation of allyl ethers

  • Biswanath Dutta,
  • Ryan Clarke,
  • Sumathy Raman,
  • Timothy D. Shaffer,
  • Laura Achola,
  • Partha Nandi,
  • Steven L. Suib

DOI
https://doi.org/10.1038/s41467-019-08619-x
Journal volume & issue
Vol. 10, no. 1
pp. 1 – 6

Abstract

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Acrylics and acrylates have become important building blocks for the chemical industry, but their efficient synthesis remains a challenge. Here, the authors report the first example of the catalytic aerobic partial oxidation of allyl ether to its acrylate ester derivative using a Li ion promoted mesoporous manganese oxide under mild conditions.