Water (May 2020)
Characterizing the Reactivity of Metallic Iron for Water Treatment: H<sub>2</sub> Evolution in H<sub>2</sub>SO<sub>4</sub> and Uranium Removal Efficiency
Abstract
Metallic iron (Fe0) has been demonstrated as an excellent material for decentralized safe drinking water provision, wastewater treatment and environmental remediation. An open issue for all these applications is the rational material selection or quality assurance. Several methods for assessing Fe0 quality have been presented, but all of them are limited to characterizing its initial reactivity. The present study investigates H2 evolution in an acidic solution (pH 2.0) as an alternative method, while comparing achieved results to those of uranium removal in quiescent batch experiments at neutral pH values. The unique feature of the H2 evolution experiment is that quantitative H2 production ceased when the pH reached a value of 3.1. A total of twelve Fe0 specimens were tested. The volume of molecular H2 produced by 2.0 g of each Fe0 specimen in 560 mL H2SO4 (0.01 M) was monitored for 24 h. Additionally, the extent of U(VI) (0.084 mM) removal from an aqueous solution (20.0 mL) by 0.1 g of Fe0 was characterized. All U removal experiments were performed at room temperature (22 ± 2 °C) for 14 days. Results demonstrated the difficulty of comparing Fe0 specimens from different sources and confirmed that the elemental composition of Fe0 is not a stand-alone determining factor for reactivity. The time-dependent changes of H2 evolution in H2SO4 confirmed that tests in the neutral pH range just address the initial reactivity of Fe0 materials. In particular, materials initially reacting very fast would experience a decrease in reactivity in the long-term, and this aspect must be incorporated in designing novel materials and sustainable remediation systems. An idea is proposed that could enable the manufacturing of intrinsically long-term efficient Fe0 materials for targeted operations as a function of the geochemistry.
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