Recent Advances in Homogeneous/Heterogeneous Catalytic Hydrogenation and Dehydrogenation for Potential Liquid Organic Hydrogen Carrier (LOHC) Systems

Abstract

Here, we review liquid organic hydrogen carriers (LOHCs) as a potential solution to the global warming problem due to the increased use of fossil fuels. Recently, hydrogen molecules have attracted attention as a sustainable energy carrier from renewable energy-rich regions to energy-deficient regions. The LOHC system is one a particularly promising hydrogen storage system in the “hydrogen economy”, and efficient hydrogen mass production that generates only benign byproducts can be applied in the industry. Therefore, this article presents hydrogenation and dehydrogenation, using homogeneous or heterogeneous catalysts, for several types of LOHCs, including formic acid/formaldehyde/ammonia, homocyclic compounds, nitrogen- and oxygen-containing compounds. In addition, it introduces LOHC system reactor types.

Keywords

• hydrogenation
• dehydrogenation
• homogeneous catalysis
• heterogeneous catalysis
• liquid organic hydrogen carrier (LOHC)