Acta Crystallographica Section E (Mar 2010)

2-Azido-3,4;6,7-di-O-isopropylidene-α-d-glycero-d-talo-heptopyranose

  • Amber L. Thompson,
  • David J. Watkin,
  • George W. J. Fleet,
  • Ken Izumori,
  • Gabriel M. J. Lenagh-Snow,
  • Sarah F. Jenkinson

DOI
https://doi.org/10.1107/S1600536810003995
Journal volume & issue
Vol. 66, no. 3
pp. o525 – o526

Abstract

Read online

In the title compound, C13H21N3O6, the six-membered ring adopts a twist-boat conformation with the azide group in the bowsprit position. The azide group is disordered over two sets of sites in a 0.642 (10):0.358 (10) ratio. The crystal structure consists of O—H...O hydrogen-bonded trimer units. The absolute configuration was determined from the use of d-mannose as the starting material.