Тонкие химические технологии (Jun 2017)

ON LIMITING THE VOLUME FRACTION OF PARTICLES IN THE DISPERSE SAMPLE (FOR THE TASkS ON CONTROLLING THEIR MAGNETIC PROPERTIES)

  • A. A. Sandulyak,
  • M. N. Polismakova,
  • D. O. Kiselev,
  • D. A. Sandulyak,
  • A. V. Sandulyak

DOI
https://doi.org/10.32362/2410-6593-2017-12-3-58-64
Journal volume & issue
Vol. 12, no. 3
pp. 58 – 64

Abstract

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It was found that it is sufficient to have the values of magnetic susceptibility X of a disperse sample containing ferroparticles to obtain the values of magnetic susceptibility Xч of its particles (particularly, in solving many scientific applied tasks of magnetic control and/or magnetophoresis of such particles). It is important that the values of volume fraction (concentration) γ of the ferroparticles be low (feasible), when simple dependence is acceptable for determining Xч values: Xч = X/γ. The question of the criterion value of γ is considered (it is still a discussion question). This value is up to γ=0.02-0.05 (this is evaluated data existing for a long time) for magnetite samples and even up to γ=0.2-0.25 (circumstantial evidence - by determining the demagnetization factor of disperse ferromagnetic samples). Direct experiments based on the ponderomotive Faraday method are realized with the use of a powder sample within the range of volume fraction γ ≤ 0.3 (for disperse phase - magnetite). The results of the experiments show that the linear part of X(γ) relation ends at γ 0.2. This is confirmed by many other consolidate data obtained by using disperse samples of magnetite (powder, colloid). However, at lower values of γ (γ ≤ 0.02-0.05) “individual” linear relation between X and γ is found as the consolidate data show. Taking into account the proportionality coefficient this relation differs from the previous relation by about 18%. This means that it is appropriate to use X values obtained at γ ≤ 0.02-0.05 for obtaining more accurate values of Xч.

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