Breaking scaling relationships in alkynol semi-hydrogenation by manipulating interstitial atoms in Pd with d-electron gain

Yang Yang; Xiaojuan Zhu; Lili Wang; Junyu Lang; Guohua Yao; Tian Qin; Zhouhong Ren; Liwei Chen; Xi Liu; Wei Li; Ying Wan

doi:10.1038/s41467-022-30540-z

Nature Communications (May 2022)

Breaking scaling relationships in alkynol semi-hydrogenation by manipulating interstitial atoms in Pd with d-electron gain

Yang Yang,
Xiaojuan Zhu,
Lili Wang,
Junyu Lang,
Guohua Yao,
Tian Qin,
Zhouhong Ren,
Liwei Chen,
Xi Liu,
Wei Li,
Ying Wan

Affiliations

Yang Yang: The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
Xiaojuan Zhu: The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
Lili Wang: The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
Junyu Lang: School of Physical Science and Technology, Shanghai Tech University
Guohua Yao: The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University
Tian Qin: School of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Jiao Tong University
Zhouhong Ren: School of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Jiao Tong University
Liwei Chen: School of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Jiao Tong University
Xi Liu: School of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Jiao Tong University
Wei Li: Department of Chemistry, Laboratory of Advanced Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, iChEM and State Key Laboratory of Molecular Engineering of Polymers, Fudan University
Ying Wan: The Education Ministry Key Laboratory of Resource Chemistry, Joint International Research Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, and Shanghai Frontiers Science Center of Biomimetic Catalysis, Shanghai Normal University

DOI: https://doi.org/10.1038/s41467-022-30540-z
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 10

Abstract

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Circumventing the linear scaling relationship in the semi-hydrogenation is challenging. Here the authors report a method for breaking the scaling relationships using ordered mesoporous carbon-supported Pd nanocatalysts with d-electron gain by p-block atoms occupying interstitial sites in the lattice as a greener alternative to Lindlar catalysts for the selective hydrogenation of alkynols.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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