Aramid nanofiber based Ag/Fe3O4-CNT/rGO hybrid membrane for high-performance electromagnetic interference shielding

Abstract

With the increase of modern integrated electronic and telecommunication systems, high-performance electromagnetic interference (EMI) shielding materials with flexibility, outstanding thermal conductive properties and superior EMI shielding performances are designed to solve the problems of electromagnetic radiation and heat accumulation. Herein, flexible asymmetric trilaminar architecture film with good mechanical properties is prepared via the facile three-step vacuum-assisted filtration (VAF) followed by hot-pressing approach, which is composed of silver-plated aramid nanofibers (ANF-Ag), ANF-Fe3O4&CNT (ANF-FC) and ANF-reduced graphene oxide (ANF-rGO) layers. The conductive ANF-Ag and ANF-rGO layers acted as the EMI shielding, thermal conductive layers, and supporting substrate layers. The magnetic ANF-FC layer played the important role in synergistically enhancing the EMI shielding performance. The resultant flexible and asymmetric trilaminar hybrid membrane with a thickness of 112 µm exhibited maximum thermal conductivity of 8.5 W m−1 K−1 and EMI SE of 67.5 dB, but also maintained a high tensile strength of 75.5 MPa and superb electrical conductivity of 2.46 × 106 S/m. This asymmetric trilaminar structures film holds great promise to addresses issues of electromagnetic radiation and heat accumulation for personal smart electronic devices, wearable electronics, electronic telecommunication systems.

Keywords

• Aramid nanofiber
• Silver-plated
• Asymmetric trilaminar structures
• Electromagnetic interference shielding
• Thermal conductivity