Polyacrylic acid tethered onto the surface of vinyl functionalized silica nanoparticles for flexible hydrogel electrolytes of sodium ion hybrid supercapacitors

Abstract

Hydrogel electrolytes, where water solvents and salts are confined in the porous networks of polymeric or inorganic solids, are attractive because they can resolve technical challenges of liquid electrolytes such as leakage, water decomposition, and mechanical instability. Herein, we demonstrate polyacrylic acid tethered onto the surface of vinyl functionalized silica nanoparticles (PAA-VSNP) hydrogel electrolytes through a sol-gel and radical polymerization process. The synthesis chemistry, the associated chemical structure, and the morphology of PAA-VSNP hydrogel electrolytes were comprehensively characterized analyzing FTIR, XPS and 13C and 29Si solid-state MAS NMR spectroscopies. The resulting PAA-VSNP hydrogel electrolytes were mechanically stable as verified by the stretchability up to 1122.75% of original length as well as ionically conductive as demonstrated by higher ionic conductivity of 20.23 mS cm−1 and lower activation energy of 0.106 eV than those of PVA counterparts. Integrating this PAA-VSNP hydrogel electrolytes with activated carbon and Na3V2(PO4)3/carbon composite and, flexible sodium ion hybrid supercapacitors (AC//PAA-VSNP //NVP@C SHSC SHSC) full cells could be fabricated. The as-fabricated AC//PAA-VSNP//NVP@C SHSC achieved a long-term cyclability over 4000 cycles and flexibility, delivering the larger energy and power densities 86.95 W h kg−1 and 19.94 kW kg−1 than those of AC//PVA//NVP@C and other works using hydrogel electrolytes.

Keywords

• Flexible hydrogels
• Aqueous electrolytes
• Organic/Inorganic hybrid
• Sodium ion storage
• Hybrid supercapacitors
• Radical polymerization