Nanomaterials (Dec 2022)

Silver Nanoparticle Chains for Ultra-Long-Range Plasmonic Waveguides for Nd<sup>3+</sup> Fluorescence

  • Javier Fernández-Martínez,
  • Sol Carretero-Palacios,
  • Pablo Molina,
  • Jorge Bravo-Abad,
  • Mariola O. Ramírez,
  • Luisa E. Bausá

DOI
https://doi.org/10.3390/nano12234296
Journal volume & issue
Vol. 12, no. 23
p. 4296

Abstract

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Plasmonic waveguides have been shown to be a promising approach to confine and transport electromagnetic energy beyond the diffraction limit. However, ohmic losses generally prevent their integration at micrometric or millimetric scales. Here, we present a gain-compensated plasmonic waveguide based on the integration of linear chains of Ag nanoparticles on an optically active Nd3+-doped solid-state gain medium. By means of dual confocal fluorescence microscopy, we demonstrate long-range optical energy propagation due to the near-field coupling between the plasmonic nanostructures and the Nd3+ ions. The subwavelength fluorescence guiding is monitored at distances of around 100 µm from the excitation source for two different emission ranges centered at around 900 nm and 1080 nm. In both cases, the guided fluorescence exhibits a strong polarization dependence, consistent with the polarization behavior of the plasmon resonance supported by the chain. The experimental results are interpreted through numerical simulations in quasi-infinite long chains, which corroborate the propagation features of the Ag nanoparticle chains at both excitation (λexc = 590 nm) and emission wavelengths. The obtained results exceed by an order of magnitude that of previous reports on electromagnetic energy transport using linear plasmonic chains. The work points out the potential of combining Ag nanoparticle chains with a small interparticle distance (~2 nm) with rare-earth-based optical gain media as ultra-long-range waveguides with extreme light confinement. The results offer new perspectives for the design of integrated hybrid plasmonic–photonic circuits based on rare-earth-activated solid-state platforms.

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