Solubility of Hydroxytyrosol in binary mixture of ethanol + water from (293.15 to 318.15) K: Measurement, correlation, dissolution thermodynamics and preferential solvation

Abdelkarim Aydi; Imen Dali; Kaouther Ghachem; Abdulaal Z. Al-Khazaal; Daniel R. Delgado; Lioua Kolsi

Alexandria Engineering Journal (Feb 2021)

Solubility of Hydroxytyrosol in binary mixture of ethanol + water from (293.15 to 318.15) K: Measurement, correlation, dissolution thermodynamics and preferential solvation

Abdelkarim Aydi,
Imen Dali,
Kaouther Ghachem,
Abdulaal Z. Al-Khazaal,
Daniel R. Delgado,
Lioua Kolsi

Affiliations

Abdelkarim Aydi: Université Paris-Sud, LETIAM, Lip (Sys)2, IUT d’Orsay, Plateau de Moulon, 91400 Orsay, France; Laboratoire Matériaux, Molécules et Applications (LMMA), Institut Préparatoire aux Etudes Scientifiques et Techniques (IPEST), Université de Carthage, Bp 51 La Marsa, 2070, Tunis, Tunisia; Corresponding authors at: Université Paris-Sud, LETIAM, Lip (Sys)2, IUT d’Orsay, Plateau de Moulon, 91400 Orsay, France (A. Aydi). Mechanical Engineering Department, College of Engineering, Ha’il University, Ha’il City, Saudi Arabia (L. Kolsi).
Imen Dali: Laboratoire Matériaux, Molécules et Applications (LMMA), Institut Préparatoire aux Etudes Scientifiques et Techniques (IPEST), Université de Carthage, Bp 51 La Marsa, 2070, Tunis, Tunisia
Kaouther Ghachem: Department of Industrial Engineering and Systems, College of Engineering, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia
Abdulaal Z. Al-Khazaal: Department of Chemical and Materials Engineering, Faculty of Engineering, Northern Border University, Arar P.O. Box 1321, Saudi Arabia
Daniel R. Delgado: Grupo de Investigaciones GRIAUCC, Programa de Ingeniería Industrial, Facultad de Ingeniería, Universidad Cooperativa de Colombia, Neiva, Colombia
Lioua Kolsi: Mechanical Engineering Department, College of Engineering, Ha’il University, Ha’il City, Saudi Arabia; Laboratory of Metrology and Energy Systems, National Engineering School of Monastir, University of Monastir, Tunisia; Corresponding authors at: Université Paris-Sud, LETIAM, Lip (Sys)2, IUT d’Orsay, Plateau de Moulon, 91400 Orsay, France (A. Aydi). Mechanical Engineering Department, College of Engineering, Ha’il University, Ha’il City, Saudi Arabia (L. Kolsi).

Journal volume & issue: Vol. 60, no. 1
pp. 905 – 914

Abstract

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Hydroxytyrosol (HXT) (also known as 3,4-dihydroxyphényléthanol,) is a biophenol extracted from olive. HXT is known for its high antioxidant significance effect. In this work, we focused on the study of the behavior of the solubility of HXT in binary solvent mixtures (ethanol + water) as well as the thermodynamic proprieties. The solubility of HXT in water, ethanol and in binary solvent mixtures (ethanol + water) was measured at five different temperatures from (293.15 to 318.15) K. The enthalpy of fusion and the melting point of HXT were experimentally determined since they are essential for the study of the of solubility and crystallization process. Thermodynamic properties of dissolution of the HXT (Gibbs energy (ΔsolG°), molar enthalpy of dissolution (ΔsolH°), and molar entropy of dissolution (ΔsolS°)) are predicted using the van’t Hoff analysis, the Gibbs equation, and the measured solubilities data. The preferential solvation has been determined using the inverse Kirkwood–Buff integral (IKBI) theory.

Published in Alexandria Engineering Journal

ISSN: 1110-0168 (Print); 2090-2670 (Online)
Publisher: Elsevier
Country of publisher: Egypt
LCC subjects: Technology: Engineering (General). Civil engineering (General)
Website: http://www.journals.elsevier.com/alexandria-engineering-journal/

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