A preliminary study of pilot-scale electrolytic reduction of UO2 using a graphite anode

Abstract

Finding technical issues associated with equipment scale-up is an important subject for the investigation of pyroprocessing. In this respect, electrolytic reduction of 1 kg UO2, a unit process of pyroprocessing, was conducted using graphite as an anode material to figure out the scale-up issues of the C anode-based system at pilot scale. The graphite anode can transfer a current that is 6–7 times higher than that of a conventional Pt anode with the same reactor, showing the superiority of the graphite anode. UO2 pellets were turned into metallic U during the reaction. However, several problems were discovered after the experiments, such as reaction instability by reduced effective anode area (induced by the existence of Cl2 around anode and anode consumption), relatively low metal conversion rate, and corrosion of the reactor. These issues should be overcome for the scale-up of the electrolytic reducer using the C anode.

Keywords

• Anode
• Carbon
• Electrolytic Reduction
• Pilot Scale
• Pyroprocessing
• Spent Fuel