Acta Crystallographica Section E (May 2010)

3-[2-(4,4-Dimethyl-2,6-dioxocyclohexylidene)hydrazinyl]benzonitrile

  • Naki Çolak,
  • Didem Aksakal,
  • Ömer Andaç,
  • Orhan Büyükgüngör

DOI
https://doi.org/10.1107/S1600536810013164
Journal volume & issue
Vol. 66, no. 5
pp. o1165 – o1166

Abstract

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The title compound, C15H15N3O2, contains benzonitrile and 4,4-dimethyl-2,6-dioxocyclohexylidene groups connected via a hydrazinyl group. The structure is in the hydrazone tautomeric form in the solid state. The benzonitrile and hydrazinyl groups (3-hydrazinylbenzonitrile) are essentially coplanar with an r.m.s. deviation of 0.016 Å. Intramolecular N—H...O hydrogen bonding helps to stabilize the molecular structure, and weak intermolecular C—H...O hydrogen bonding is present in the crystal structure.