Acta Crystallographica Section E (May 2010)

[O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)

  • Primjira P. Tadbuppa,
  • Edward R. T. Tiekink

DOI
https://doi.org/10.1107/S160053681001189X
Journal volume & issue
Vol. 66, no. 5
pp. m498 – m498

Abstract

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The title compound, [Au(C9H9ClNOS)(C18H33P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S—Au—P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the ethoxy group.