Mechanical properties and solidification mechanism of coal gangue-granulated blast furnace slag geopolymer stabilized engineering slurry

Abstract

This study utilizes polymers based on coal gangue and blast furnace slag to solidify engineering slurry with high silt content. Response surface methodology was employed to investigate the effects of polymer composition, alkali activator modulus, and coal gangue calcination temperature on the unconfined compressive strength of stabilized soil. Additionally, the study comprehensively characterized the thermal stability, pore structure, molecular bonds, mineral composition, and micro-morphology of the stabilized soils, and explored the mechanisms governing their strength development. The results demonstrate that the highest strength of stabilized soils is achieved with a slag to coal gangue ratio of 2.5:7.5, a water glass modulus of 1.2, and a coal gangue calcination temperature of 750°C. Formation of calcium-aluminum-silicate-hydrate (C-A-S-H) and sodium-aluminum-silicate-hydrate (N-A-S-H) contributes significantly to the strength development. The presence of slag promotes early strength through C-A-S-H formation, while coal gangue facilitates N-A-S-H formation, supporting later-stage strength development by filling micropores. By applying alkali-activated calcined coal gangue-slag based cementitious materials to solidify engineering slurry, this research not only elucidates the mechanism of alkali-activated calcined coal gangue-granulated blast furnace slag in slurry solidification but also promotes the utilization of industrial solid waste, providing new insights for environmental protection and resource recovery.

Keywords

• Calcined coal gangue
• Granulated blast furnace slag
• Mechanical properties
• Engineering slurry
• Response surface methodology