Nature Communications (Nov 2022)

Valence-skipping and quasi-two-dimensionality of superconductivity in a van der Waals insulator

  • Caorong Zhang,
  • Junwei Huang,
  • Kun Zhai,
  • Keivan Akhtari,
  • Zhiwei Shen,
  • Lingyi Ao,
  • Zeya Li,
  • Feng Qin,
  • Yukai Chang,
  • Ling Zhou,
  • Ming Tang,
  • Xueting Dai,
  • Caiyu Qiu,
  • Yi Zhang,
  • Lin Wang,
  • Zhongyuan Liu,
  • Yongjun Tian,
  • Mohammad Saeed Bahramy,
  • Hongtao Yuan

DOI
https://doi.org/10.1038/s41467-022-34726-3
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 9

Abstract

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Fluctuation of the cation valence state plays a crucial role in emergent quantum phenomena in correlated electron systems. Here, the authors demonstrate a valence-fluctuation-driven insulator-to-superconductor transition in the van der Waals insulator GeP as a function of hydrostatic pressure.