Scientific Reports (Apr 2017)

Excitation Intensity Dependent Carrier Dynamics of Chalcogen Heteroatoms in Medium-Bandgap Polymer Solar Cells

  • Chandramouli Kulshreshtha,
  • Jiwon Son,
  • Torbjörn Pascher,
  • Ji-Hee Kim,
  • Taiha Joo,
  • Jaewon Lee,
  • Mun Seok Jeong,
  • Kilwon Cho

DOI
https://doi.org/10.1038/s41598-017-00834-0
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 9

Abstract

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Abstract The excitation intensity dependent carrier dynamics of blends with PC[70]BM of three new medium-band gap conjugated polymers with central chalcogen heteroatoms, PBDTfDTBX (X = O, T(Sulphur), Se) were studied. The PBDTfDTBX polymers (Poly[4,8-bis(5-(2-butyloctyl)thiophene-2-yl)benzo[1,2-b;4,5-b′]dithiophene-alt-4,7-bis(4-(2-ethylhexyl)-2-thienyl)-dithieno[3′,2′:3,4;2″,3″:5,6]benzo[1,2-c][1,2,5] furazan or thiadiazole or selenadiazole]) have symmetrical structures but exhibit different solar cell performances. In this study, we determined how the photogenerated charge carrrier dynamics of the PBDTfDTBX:PC[70]BM blends varies with the heteroatom by performing transient absorption measurements at various excitation intensities. It was found that the charge carrier dynamics of the PBDTfDTBX blends with X = T or Se heteroatoms are dependent on the excitation intensity whereas that of the PBDTfDTBO blend is independent of the intensity. The photogenerated charge carrier dynamics of the PBDTfDTBO:PCBM, PBDTfDTBT:PCBM, and PBDTfDTBSe:PCBM blends were all modeled globally and rates were estimated for different photophysical processes occurring on different time scales.