Acta Crystallographica Section E (Oct 2012)

N-Ferrocenylmethyl-2-nitroaniline

  • Oumelkheir Rahim,
  • Abdelhamid Khelef,
  • Belgacem Terki,
  • Mohammed Sadok Mahboub,
  • Touhami Lanez

DOI
https://doi.org/10.1107/S1600536812039177
Journal volume & issue
Vol. 68, no. 10
pp. m1318 – m1318

Abstract

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In the title compound, [Fe(C5H5)(C12H11N2O2)], the two cyclopentadienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitrobenzenamine group, which is essentially perpendicular to the substituted cyclopentadienyl ring, with an N—C(H2)—C—C torsion angle of 89.8 (2)°. Intramolecular N—H...O and N—H...N hydrogen bonds occur. In the crystal, weak C—H...O hydrogen bonds link adjacent molecules.