Removal of Pb(II) Ions from Wastewater by Using Polyethyleneimine-Functionalized Fe₃O₄ Magnetic Nanoparticles

Abstract

A class of polyethyleneimine (PEI)-functionalized Fe3O4 magnetic nanoparticles (MNPs) has been facilely produced through a solvothermal process. The synthetic MNPs have been characterized by multiple technologies and then used for Pb(II) ion sorption from the aqueous media in different conditions. It was found the Pb(II) adsorption behaviors could be well fitted by the pseudo second-order kinetic and Langmuir isotherm models. The maximum Pb(II) adsorption capacity at 25 °C and pH 5.0 was calculated to be 60.98 mg/g. Moreover, effects of temperature, pH, and electrolyte of aqueous phase on the Pb(II) adsorption capacity of MNPs have been carefully examined. The Pb(II) adsorbing capacity was enhanced with temperature or pH rising, but reduced with the addition of various electrolytes. Additionally, the recyclability of synthetic MNPs has been also assessed. The prepared PEI-functionalized MNPs could still maintain good adsorption performance after five cycles of Pb(II) removal. These results indicated that the PEI-functionalized Fe3O4 MNPs could be readily synthesized and served as a desirable and economic adsorbent in Pb(II)-contaminated wastewater treatment.

Keywords

• magnetic nanoparticles
• polyethyleneimine
• pb(ii) ion adsorption
• recyclability