Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution

Rufan Chen; Yang Wang; Yuan Ma; Arindam Mal; Xiao-Ya Gao; Lei Gao; Lijie Qiao; Xu-Bing Li; Li-Zhu Wu; Cheng Wang

doi:10.1038/s41467-021-21527-3

Nature Communications (Mar 2021)

Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution

Rufan Chen,
Yang Wang,
Yuan Ma,
Arindam Mal,
Xiao-Ya Gao,
Lei Gao,
Lijie Qiao,
Xu-Bing Li,
Li-Zhu Wu,
Cheng Wang

Affiliations

Rufan Chen: Sauvage Center for Molecular Sciences and Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University
Yang Wang: Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
Yuan Ma: Beijing Advanced Innovation Center for Materials Genome Engineering, Institute for Advanced Materials and Technology, University of Science and Technology Beijing
Arindam Mal: Sauvage Center for Molecular Sciences and Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University
Xiao-Ya Gao: Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
Lei Gao: Beijing Advanced Innovation Center for Materials Genome Engineering, Institute for Advanced Materials and Technology, University of Science and Technology Beijing
Lijie Qiao: Beijing Advanced Innovation Center for Materials Genome Engineering, Institute for Advanced Materials and Technology, University of Science and Technology Beijing
Xu-Bing Li: Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
Li-Zhu Wu: Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
Cheng Wang: Sauvage Center for Molecular Sciences and Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University

DOI: https://doi.org/10.1038/s41467-021-21527-3
Journal volume & issue: Vol. 12, no. 1
pp. 1 – 9

Abstract

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Covalent organic frameworks (COFs) present well-defined materials for constructing structure-property-activity relationships. Herein, authors explore isostructural porphyrinic two-dimensional COFs with tunable of photocatalytic H2 production rates arising from tailored charge-carrier dynamics.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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