Minerals (Jan 2021)
Long-Term Strength Evolution in Ambient-Cured Solid-Activator Geopolymer Compositions
Abstract
The major downsides of cement manufacturing are the high CO2 emissions and high energy usage. Geopolymers, which are fabricated by activation of blends of fly ash (FA) and ground granulated blast furnace slag (GGBFS) using an alkaline activator, offer a promising solution to this issue. However, to enhance the replacement of cement in construction applications, geopolymer compositions have to be designed such that they can be activated on site by just adding water, similar to how cements are used. Therefore, the present work uses solid sodium metasilicate (MS, Na2SiO3) as the alkaline activator in order to design an add-water-style FA/GGBFS-based geopolymer composition. These compositions were designed by optimising the binder (FA/GGBFS) ratio, Na2SiO3/binder ratio, and water/binder ratio individually to assess the effects of these parameters on the setting times and mechanical (flexural and compressive) strengths over extended curing times (three months). The major factors affecting the strength development and setting times (initial and final) were the amounts of GGBFS and Na2SiO3, with the former demonstrating the more dominant effect. The consistent strength development with curing time was attributed to calcium aluminium silicate hydrate (CASH) gel formation in the early curing times which was affected by the slag addition levels, and sodium aluminium silicate hydrate (NASH) gel formation at later curing times which was influenced by the metasilicate addition levels. The metasilicate amounts were observed to impact on CASH gel formation in early stage curing. Geopolymer compositions with FA/GGBFS ratio of 35/65 and MS/water ratios of 0.2 showed high compressive strengths of ~70 MPa at 28 days, which are superior to values seen in conventional ordinary Portland cement (OPC) mixes for the same curing times.
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