Piezoelectric Effect Enhanced Photocatalytic Activity of Pt/Bi_3.4Gd_0.6Ti₃O₁₂ Plasmonic Photocatalysis

Abstract

Novel Pt/Bi3.4Gd0.6Ti3O12 heterojunction was synthesized by a decoration of Pt nanoparticles (PtNPs) on the surface of piezoelectric Bi3.4Gd0.6Ti3O12 (BGTO) through an impregnation process. The photocatalytic, piezo-catalytic, and piezo-photocatalytic activities of the Pt/BGTO heterojunction for methyl orange (MO) degradation were investigated under ultrasonic excitation and whole spectrum light irradiation. The internal piezoelectric field of BGTO and a plasmonic effect have been proven important for the photocatalytic activity of the heterojunctions. Pt/BGTO exhibited an optimum photocatalytic degradation performance of 92% for MO in 70 min under irradiation of whole light spectrum and ultrasonic coexcitation, and this value was about 1.41 times higher than the degradation rate under whole spectrum light irradiation alone. The PtNPs in Pt/BGTO heterojunction can absorb the incident light intensively, and induce the collective oscillation of surface electrons due to the surface plasmon resonance (SPR) effect, thus generating “hot” electron–hole pairs. The internal piezoelectric field produced in BGTO by ultrasonic can promote the separation of SPR-induced “hot” charge carriers and facilitate the production of highly reactive oxidation radicals, thus enhancing Pt/BGTO heterojunction′s photocatalytic activity for oxidizing organic dyes.

Keywords

• bismuth titanate
• Pt nanoparticles
• heterojunction
• piezoelectric effect
• plasmonic effect