Scientific Reports (May 2024)
Effect of high temperature on mechanical properties of lithium slag concrete
Abstract
Abstract As the main gel material of concrete, cement is used in an astonishing amount every year in the construction industry. However, a large amount of CO2 is emitted into the atmosphere while producing cement. Therefore, it is the general trend to look for substitutes for cement and develop new green concrete. Lithium slag (LS) is the industrial waste discharged from lithium salt plants. Through testing, it is found that the chemical composition of LS has a high degree of coincidence with ordinary Portland cement (OPC) Therefore, LS can be incorporated into concrete as supplementary cementations material (SCM) to prepare lithium slag concrete (LSC). The pollution of the natural environment caused by a large number of piled-up and landfilled LS is immeasurable. Consuming and using LS in large quantities and with high efficiency not only eliminates the pollution of lithium slag to the natural environment, but also helps to reduce the amount of cement used in green concrete and truly reuse waste resources. In order to study the mechanical properties of post-heated LSC, the test were carried out for LSC specimens after high-temperature. The main influence factors were considered, including the temperatures of 20℃, 100 ℃, 300 ℃, 500 ℃ and 700 ℃, the contents of lithium slag in LSC of 0%, 10%, 20% and 30%, cooling method of LSC after exposure high temperature. The results showed that the mechanical properties of LS concrete specimens were slightly improved at 100 ℃, and when the temperature was 300 ℃ or higher, the damage to the specimens was huge and irreversible. An appropriate amount of LS (20% lithium slag content) could improve the strength of LSC. This paper also studied the relationship between lithium slag content and strengths of LS concrete. The research results show that adding an appropriate amount of LS to concrete improves the mechanical properties of concrete. When the LS replacement rate is 20%, the mass loss rate of LSC after different high temperature treatments was the minimum. The cubic compressive strength, axial compressive strength, and flexural strength of specimens with 20% LS substitution can be increased by 8.16%, 8.33%, and 13.46% after high temperature. The cubic compressive strength, axial compressive strength, and flexural strength of specimens with 20% LS substitution can be increased by 8.16%, 8.33%, and 13.46% after high temperature.
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