Synthesis of Cu and Zr-based coordination polymers with N/O donors and investigation of their photocatalytic activity against dye

Abstract

The coordination polymers (CPs) of Cu and Zr were synthesized by the hydrothermal method. The orotic acid potassium salt (H3KL) was used as a linker, which coordinates via O–O. Whereas, 4,4′-trimethylenedipyridine (4,4′-TMDP) was used as a bifunctional monomer, which coordinates via N–N. The synthesized CPs were characterized by FTIR, P-XRD, TGA, DSC and SEM. The photocatalytic activity was investigated against methylene blue (MB) under sunlight irradiation. Both Cu-CP and Zr-CP exhibited potential activity for the degradation of MB, which was 72 % for Cu-CP and 93 % for Zr-CP. The band gap of the CPs was also investigated, and the observed value was 2.2 eV. The band gap indicates that these compounds could bring breakthroughs as photocatalysts instead of semiconductors. These kinds of CPs could be used for multiple purposes in industry and in a green environment.

Keywords

• Coordination polymer
• Photocatalysis
• Powder-XRD
• SEM
• Methylene blue