Química Nova (Oct 2007)

Estudo comparativo da eficiência da difenilcarbazida e do óleo de coco saponificado microemulsionados na inibição da corrosão de aço carbono Comparative effectiveness microemulsions of diphenylcarbazide and saponified coconut oil in the carbon steel corrosion inhibition process

  • Cátia G. F. T. Rossi,
  • Hélio Scatena Jr,
  • Maria Aparecida M. Maciel,
  • Tereza N. C. Dantas

DOI
https://doi.org/10.1590/S0100-40422007000500014
Journal volume & issue
Vol. 30, no. 5
pp. 1128 – 1132

Abstract

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The effectiveness of microemulsions (ME) of saponified coconut oil (OCS-ME) and diphenylcarbazide (DC-ME) on a carbon steel corrosion inhibition process was evaluated using an electrochemical method of polarization resistance. The ME was prepared with OCS, butanol, kerosene and saline solutions. OCS-ME and DC-ME showed highest inhibitions effects (77% and 92%, respectively) at lower concentrations (0.5% and 0.48 - 0.50%, respectively). The surfactant OCS (in H2O) showed lower efficiency (63% at 0.20 - 0.25% concentration). The greatest inhibitory effect of DC-ME could be correlated with the chemical structure and the rich O/W ME system, which are very important for adsorption phenomena in interfacial ME systems.

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