Ultrafast lattice dynamics and electron–phonon coupling in platinum extracted with a global fitting approach for time-resolved polycrystalline diffraction data

Abstract

Quantitative knowledge of electron–phonon coupling is important for many applications as well as for the fundamental understanding of nonequilibrium relaxation processes. Time-resolved diffraction provides direct access to this knowledge through its sensitivity to laser-induced lattice dynamics. Here, we present an approach for analyzing time-resolved polycrystalline diffraction data. A two-step routine is used to minimize the number of time-dependent fit parameters. The lattice dynamics are extracted by finding the best fit to the full transient diffraction pattern rather than by analyzing transient changes of individual Debye–Scherrer rings. We apply this approach to platinum, an important component of novel photocatalytic and spintronic applications, for which a large variation of literature values exists for the electron–phonon coupling parameter G ep. Based on the extracted evolution of the atomic mean squared displacement and using a two-temperature model, we obtain G ep = ( 3.9 ± 0.2 ) × 10 17 W m 3 K (statistical error). We find that at least up to an absorbed energy density of 124 J/cm3, G ep is not fluence-dependent. Our results for the lattice dynamics of platinum provide insights into electron–phonon coupling and phonon thermalization and constitute a basis for quantitative descriptions of platinum-based heterostructures in nonequilibrium conditions.