Abrupt Geographic Shift in Hydrogen Isotope Ratios of Meteoric Water Across the Western Andes, Peru

Abstract

Abstract Quantitative isotopic paleoaltimetry has been applied in regions where Rayleigh distillation controls isotopic lapse rates. Air mass mixing and moisture recycling are viewed as complicating factors. We show here that, because of such effects, a cross‐Andean transect of meteoric water δD values precisely marks the geographic position of the Western Cordillera crest. This modern water signal is also recorded in Pliocene‐Pleistocene hydrated volcanic glass δD values. δD values between the Pacific coast and Western Cordillera exhibit no trend up to 2.5 km elevation and 100 km inboard, consistent with an arid climate in which Amazonian moisture is topographically blocked and Pacific moisture is efficiently recycled. The result is a large δD lapse rate (−98‰/km) and an abrupt horizontal δD shift (2‰/km) at the Western Cordillera crest. Therefore, we conclude that cross‐orogen δD transects could locate the ancient Western Cordillera crest.

Keywords

• stable isotopes
• Peruvian Central Andes
• air mass mixing
• paleoaltimetry
• volcanic arc
• Altiplano