Improved Lithium Storage Performance of a TiO₂ Anode Material Doped by Co

Abstract

TiO2 is a promising anode material for lithium-ion batteries (LIBs) due to its low cost, suitable operating voltage, and excellent structural stability. The inherent poor electron conductivity and low ion diffusion coefficient, however, severely limit its application in lithium storage. Here, Co-doped TiO2 is synthesized by a hydrothermal method as an anode material since Co@TiO2 possesses a large specific surface area and high electronic conductivity. Thanks to the Co dopants, the ion diffusion and electron transport are both greatly improved, which is very beneficial for cycle stability, coulombic efficiency (CE), reversible capacity, and rate performance. As a result, Co@TiO2 shows a high reversible capacity of 227 mAh g−1 at 3 C, excellent rate performance, and cycling stability with a capacity of about 125 mAh g−1 at 10C after 600 cycles (1 C = 170 mA g−1).

Keywords

• TiO₂
• Co ion doping
• lithium-ion batteries
• lithium storage performance
• kinetic analysis