IUCrData (Sep 2019)
Poly[(μ4-phenylphosphonato)zinc(II)]
- Larry Falvello,
- Paolo Lotti,
- Chiara Massera,
- Serena C. Tarantino,
- Michele Zema,
- Horst Puschmann,
- Marielle Y. Agbahoungbata,
- Jacopo Andreo,
- Suchithra Ashoka Sahadevan,
- Alessandro Bismuto,
- Giulia Bonfant,
- Sourou A. S. Bonou,
- Claudia Carraro,
- Marta De Zotti,
- Armando di Biase,
- Riccardo Fantini,
- Ilaria Ferraboschi,
- Jean Marcos Ferreira Custodio,
- Matteo Frigerio,
- Gianpiero Gallo,
- Silvana Gjyli,
- Meriem Goudjil,
- Fernando Igoa,
- Enver Kahveci,
- Maksim Kalienko,
- Sofia Lorenzon,
- Ludovico Macera,
- Joaqun Joaqun Manrique Fajardo,
- Enida Nushi,
- Said Ouaatta,
- Emmanuele Parisi,
- Leonardo Pasqualetto,
- Edyta Pesko,
- Giovanni Pierri,
- Roberta Pinalli,
- Romy Poppe,
- Antonio Santoro,
- Ekaterina Smirnova,
- Simona Sorbara,
- Leonardo Tensi,
- Gers Tusha
Affiliations
- Larry Falvello
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Paolo Lotti
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Chiara Massera
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Serena C. Tarantino
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Michele Zema
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Horst Puschmann
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Marielle Y. Agbahoungbata
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Jacopo Andreo
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Suchithra Ashoka Sahadevan
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Alessandro Bismuto
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Giulia Bonfant
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Sourou A. S. Bonou
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Claudia Carraro
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Marta De Zotti
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Armando di Biase
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Riccardo Fantini
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Ilaria Ferraboschi
- Department of Inorganic Chemistry, University of Zaragoza, Zaragoza, Spain
- Jean Marcos Ferreira Custodio
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Matteo Frigerio
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Gianpiero Gallo
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Silvana Gjyli
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Meriem Goudjil
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Fernando Igoa
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Enver Kahveci
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Maksim Kalienko
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Sofia Lorenzon
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Ludovico Macera
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Joaqun Joaqun Manrique Fajardo
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Enida Nushi
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Said Ouaatta
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Emmanuele Parisi
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Leonardo Pasqualetto
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Edyta Pesko
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Giovanni Pierri
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Roberta Pinalli
- Department of Inorganic Chemistry, University of Zaragoza, Zaragoza, Spain
- Romy Poppe
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Antonio Santoro
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Ekaterina Smirnova
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Simona Sorbara
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Leonardo Tensi
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- Gers Tusha
- AIC School 2019 – Crystallographic Information Fiesta, Naples, Italy
- DOI
- https://doi.org/10.1107/S2414314619012227
- Journal volume & issue
-
Vol. 4,
no. 9
p. x191222
Abstract
The title two-dimensional coordination polymer, [Zn(C6H5PO3)]n, was synthesized serendipitously by reacting a tetraphosphonate cavitand Tiiii[C3H7, CH3, C6H5] and Zn(CH3COO)2·2H2O in a DMF/H2O mixture. The basic conditions of the reaction cleaved the phosphonate bridges at the upper rim of the cavitand, making them available for reaction with the zinc ions. The coordination polymer can be described as an inorganic layer in which zinc coordinates the oxygen atoms of the phosphonate groups in a distorted tetrahedral environment, while the phenyl groups, which are statistically disordered over two orientations, point up and down with respect to the layer. The layers interact through van der Waals interactions. The crystal studied was refined as a two-component twin.
Keywords
