Nature Communications (Oct 2017)

Anomalous elastic properties across the γ to α volume collapse in cerium

  • Magnus J. Lipp,
  • Zs. Jenei,
  • H. Cynn,
  • Y. Kono,
  • C. Park,
  • C. Kenney-Benson,
  • W. J. Evans

DOI
https://doi.org/10.1038/s41467-017-01411-9
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 8

Abstract

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The origin of the volume collapse of cerium, the only elemental metal with a critical point in the solid phase, remains elusive. Here the authors show that, near the critical point, the f-electrons make cerium lose its compressive strength while maintaining a finite shear strength—which makes cerium unexpectedly auxetic.