Trichlorido-1κ2Cl,2κCl-(2,6-dimethylphenolato-2κO)-μ-oxido-bis{1,2(η5)-2,3,4,5-tetramethyl-1-[4-(trimethylsilyl)phenyl]cyclopentadienyl}dititanium(IV)

Abstract

The title dinuclear titanocene, [Ti2(C8H9O)(C18H25Si)2Cl3O], contains one Ti atom tetrahedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclopentadienyl ligand, and another Ti atom tetrahedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethylphenolate ligand and the substituted cyclopentadienyl ligand. The bridging O atom lies on a twofold rotation axis.