Química Nova (Mar 2015)

NOVEL SUPERABSORBENT HYDROGEL COMPOSITE BASED ON POLY(ACRYLAMIDE-CO-ACRYLATE)/NONTRONITE: CHARACTERIZATION AND SWELLING PERFORMANCE

  • Renan C. F. Leitão,
  • Cícero P. de Moura,
  • Lindomar R. D. da Silva,
  • Nágila M. P. S. Ricardo,
  • Judith P. A. Feitosa,
  • Edvani C. Muniz,
  • André R. Fajardo,
  • Francisco H. A. Rodrigues

DOI
https://doi.org/10.5935/0100-4042.20150008
Journal volume & issue
Vol. 38, no. 3
pp. 370 – 377

Abstract

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A novel superabsorbent hydrogel (SH) composite based on a poly(acrylamide-co-acrylate) matrix filled with nontronite (NONT), a Fe(III)-rich member of the smectite group of clay minerals, is described in this manuscript. A variety of techniques, including FTIR, XRD, TGA, and SEM/EDX, were utilized to characterize this original composite. Experimental data confirmed the SH composite formation and suggested NONT was completely dispersed in the polymeric matrix. Additionally, NONT improved the water uptake capacity of the final material, which exhibited fast absorption, low sensitivity to the presence of salt, high water retention and a pH sensitive properties. These preliminary data showed that the original SH composite prepared here possesses highly attractive properties for applications in areas such as the agriculture field, particularly as a soil conditioner.

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