Torrefaction of Willow in Batch Reactor and Co-Firing of Torrefied Willow with Coal

Abstract

The torrefaction process represents a thermal conversion technique conducted at relatively low temperatures ranging between 200 to 300 °C. Its objective is to produce fuel with a higher energy density by decomposing the reactive portion of hemicellulose. In this study, the kinetics of mass loss during torrefaction were investigated for willow. The experiments were carried out under isothermal conditions using thermogravimetric analysis. Batch torrefaction reactor designs were conducted and explained in detail. Co-combustion of willow with hard coal (origin: Katowice mine) in different mass ratios (25% biomass + 75% coal, 50% biomass + 50% coal, and 75% biomass + 25% coal) was conducted in addition to raw biomass torrefaction. TG/MS analysis (a combination of thermogravimetric analysis with mass spectrometry analysis) was performed in the research. The optimal torrefaction conditions for willow were identified as an average temperature of 245 °C and a residence time of 14 min, resulting in the lowest mass loss (30.15%). However, it was noted that the composition of torgas, a by-product of torrefaction, presents challenges in providing a combustible gas with sufficient heat flux to meet the energy needs of the process. Prolonged residence times over 15 min and higher average temperatures above 250 °C lead to excessive energy losses from volatile torrefaction products, making them suboptimal for willow. On the other hand, the co-combustion of torrefied biomass with hard coal offers advantages in reduced sulfur emissions but can lead to increased NOx emissions when biomass with a higher nitrogen content is co-combusted in proportions exceeding 50% biomass. This paper summarizes findings related to optimizing torrefaction conditions, challenges in torgas composition, and the emissions implications of co-combustion.

Keywords

• torrefaction
• co-torrefaction
• biochar
• reactor design
• TGA-FTIR
• TG/MS