Nature Communications (Apr 2019)
Porous metal-metalloporphyrin gel as catalytic binding pocket for highly efficient synergistic catalysis
Abstract
Synergistic catalysis occurring in an enzyme pocket shows enhanced performance through supramolecular recognition and flexibility. Here the authors design an enzyme-mimic strategy to develop a Co(II) metal-metalloporphyrin gel with excellent synergistically catalytic performance and chemo/stereo selectivity.