Nature Communications (Jan 2022)
Mechanically robust supramolecular polymer co-assemblies
Abstract
Reversible assembly of supramolecular polymers renders these materials with healing and recycling properties but mechanical properties are often inferior to those of conventional plastics. Here, the authors demonstrate that strong and tough but healable materials can be accessed through the combination of metallosupramolecular polymers with complementary mechanical properties that feature the same metal-ligand complex as binding motif