Investigation of Polymer Gel Reinforced by Oxygen Scavengers and Nano-SiO₂ for Flue Gas Flooding Reservoir

Abstract

Polymer gel plugging is an effective technique for gas mobility control in flue gas flooding reservoirs. However, the performance of polymer gels is extremely susceptible to the injected flue gas. A reinforced chromium acetate/partially hydrolyzed polyacrylamide (HPAM) gel, using thiourea as the oxygen scavenger and nano-SiO2 as the stabilizer, was formulated. The related properties were evaluated systematically, including gelation time, gel strength, and long-term stability. The results indicated that the degradation of polymers was effectively suppressed by oxygen scavengers and nano-SiO2. The gel strength would be increased by 40% and the gel kept desirable stability after aging for 180 days at elevated flue gas pressures. Dynamic light scattering (DLS) analysis and Cryo-scanning electron microscopy (Cryo-SEM) revealed that nano-SiO2 was adsorbed on polymer chains by hydrogen bonding, which improved the homogeneity of gel structure and thus enhanced the gel strength. Besides, the compression resistance of gels was studied by creep and creep recovery tests. The failure stress of gel with the addition of thiourea and nanoparticles could reach up to 35 Pa. The gel retained a robust structure despite extensive deformation. Moreover, the flow experiment indicated that the plugging rate of reinforced gel still maintained up to 93% after flue gas flooding. It is concluded that the reinforced gel is applicable for flue gas flooding reservoirs.

Keywords

• flue gas
• reinforced gel
• oxygen scavenger
• nano-SiO₂
• degradation
• long-term stability