Nature Communications (Oct 2017)

Few-femtosecond passage of conical intersections in the benzene cation

  • M. C. E. Galbraith,
  • S. Scheit,
  • N. V. Golubev,
  • G. Reitsma,
  • N. Zhavoronkov,
  • V. Despré,
  • F. Lépine,
  • A. I. Kuleff,
  • M. J. J. Vrakking,
  • O. Kornilov,
  • H. Köppel,
  • J. Mikosch

DOI
https://doi.org/10.1038/s41467-017-01133-y
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 7

Abstract

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Attosecond science is beginning to provide the tools to study the previously unattainable crucial first few femtoseconds of photochemical reactions. Here, the authors investigate extremely rapid population transfer via conical intersections in the excited benzene cation, both by experiment and computation.