Dissemination and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in water and sediment of Buriganga and Dhaleswari rivers of Dhaka, Bangladesh

Abstract

Concentration, source, ecological and health risks of sixteen polycyclic aromatic hydrocarbons (PAHs) were estimated for water and sediment samples of two urban rivers namely Buriganga River (BR) and Dhaleswari River (DR). The mean concentration of ∑PAHs in BR water and sediment were 9619.2 ngL−1 and 351.6 ngg−1, respectively. Furthermore, the average PAH concentrations detected in DR water and sediment were 1979.1 ngL−1 and 792.9 ngg−1, respectively. The composition profile showed that 3-ring PAHs were dominant in the water matrix; however, 5-ring PAHs were prevalent in the sediment samples of both rivers. Sources apportion study of PAHs indicated that mixed combustion and petroleum sources are responsible for PAHs contamination in the rivers. Ecological risk study of water suggested that the aquatic lives of both rivers are threatened by Fla, BbF, BkF, DahA, and IcdP, as presented above the threshold level. Comparison with sediment quality guidelines (SQGs) indicated that adverse effects might cause occasionally in the sediment ecosystem in DR at certain sampling sites for Nap, Acy, Fl, Phe, Ant, Pyr, Chr, BaP, and DahA. On the other hand, the presence of Nap, Acy and DahA might occasionally cause adverse biological effects in the BR sediment ecosystem. Estimated hazard quotient (HI > 1) and carcinogenic risk (CRtotal > 10−4) values indicated that local inhabitants living in the vicinity of the rivers are prone to high health risks.

Keywords

• Polycyclic aromatic hydrocarbons (PAHs)
• Isomeric ratio
• Toxic equivalent concentrations (TEQcarc)
• Ecological risk assessment
• Health risk assessment
• GC/MS